01 - Preheat oven to 350°F. Line a 12-cup muffin tin with paper liners.
02 - In a mixing bowl, whisk together the all-purpose flour, cocoa powder, granulated sugar, baking soda, baking powder, and salt until evenly distributed.
03 - Add the buttermilk, vegetable oil, eggs, and vanilla extract to the dry mixture. Mix until just combined, then pour in the hot water and stir until the batter is smooth. The batter will be thin — this is normal.
04 - Divide the batter evenly among the prepared liners, filling each about two-thirds full.
05 - Bake for 18 to 20 minutes, or until a toothpick inserted into the center comes out clean. Transfer the cupcakes to a wire rack and let them cool completely.
06 - Beat the softened butter with an electric mixer until light and creamy. Add the powdered sugar and beat for 1 minute. Mix in the marshmallow creme and vanilla extract, beating until the filling is fluffy. If the consistency is too stiff, add milk one teaspoon at a time until it reaches a pipable texture.
07 - Using a small knife or cupcake corer, remove a small portion from the center of each cooled cupcake, reserving the tops if desired. Transfer the cream filling to a piping bag and fill each cavity. Replace the reserved tops if using.
08 - Heat the heavy cream in a small saucepan until steaming but not boiling. Pour the hot cream over the semi-sweet chocolate chips and let it sit for 2 minutes. Stir until the ganache is smooth and glossy.
09 - Spoon the ganache over each cupcake or dip the tops directly into the ganache to coat evenly. Set aside and allow the glaze to set.
10 - Mix the powdered sugar with milk until a smooth but pipeable icing forms. Transfer to a piping bag fitted with a fine tip, or use a zip-top bag with a tiny corner snipped off. Pipe the classic swirl pattern across the top of each glazed cupcake.
11 - Allow the ganache and icing to fully set before serving. Enjoy at room temperature for the best texture and flavor.